Compton Effect Calculator
Compton Effect Calculator
The wavelength shift Δλ = (h/mₑc)(1 − cos θ), plus the scattered photon’s energy, the electron’s recoil energy and the angle it leaves at — and the point that catches everybody: the shift in nanometres does not depend on the incident wavelength at all, only on the angle.
Scatter a photon off a free electron at angle θ
Compton’s own 1923 case: the molybdenum Kα line at 0.708 Å (70.8 pm), scattered through 90° by graphite
One formula for the photon, two more for the electron it hit
- h/mₑc
- the Compton wavelength of the electron, 2.426 310 235 38(76) pm. It is a property of the electron and of nothing else — not of the photon, not of the target material. This is the single fact that makes the formula so persuasive: a length built from h, me and c predicts an X-ray measurement
- (1 − cos θ)
- runs from 0 at θ = 0 to 2 at θ = 180°, so the shift runs from zero to twice the Compton wavelength and never further. Often written 2sin²(θ/2), which is the same thing and is the form Compton used
- Δλ
- an ABSOLUTE shift in length, the same 2.43 pm at 90° whether the photon arrived with 1 keV or 10 MeV. What changes with energy is how big that shift is compared with the wavelength: 0.2 per cent for a 1 keV photon, 1957 per cent for a 10 MeV one
- α = E/mₑc²
- the photon energy measured in units of the electron rest energy, 510.999 keV. When α is small the electron barely recoils and E′ ≈ E; when α is large the photon loses most of its energy in one hit
- φ
- the angle the electron leaves at, on the other side of the original direction. It runs the other way from θ: forward scattering of the photon (small θ) throws the electron out sideways at nearly 90°, and backscatter (θ = 180°) drives it straight forward at φ = 0
- free and at rest
- the assumption underneath all three formulas, and false on both counts. Both approximations are excellent for an outer electron hit by an X-ray and poor for a tightly bound inner one, and the difference shows up in a real spectrum as an unshifted line beside the shifted one
Worked example
Compton’s own 1923 case: the molybdenum Kα line at 0.708 Å (70.8 pm), scattered through 90° by graphite
THE CONSTANT. h/mec = 6.626 070 15×10−34 ÷ (9.1093837139×10−31 × 2.99792458×108) = 2.426 310 pm = 0.024 263 Å. Compton calculated 0.0242 Å from the constants he had; the agreement to three figures is the measurement of h, m and c in disguise.
THE ANGLE FACTOR. cos 90° = 0, so (1 − cos θ) = 1 exactly. At this one angle the formula has no trigonometry left: Δλ = h/mec = 2.426 310 pm. That is the headline, and it is why 90° is the angle to measure at.
THE SCATTERED WAVELENGTH. λ′ = 70.8 + 2.4263 = 73.2263 pm, which is 0.732 26 Å. The shift is 3.427 per cent of the incident wavelength — small, but a 1923 crystal spectrometer could resolve it, and that is the entire reason the experiment was done with X-rays rather than light.
THE ENERGIES. E = 1239 841.98/70.8 = 17.5119 keV and E′ = 1239 841.98/73.2263 = 16.9316 keV, so the electron carries away 580.2 eV — 3.313 per cent of the photon’s energy. Notice that the energy share and the wavelength share are not the same number (3.313 against 3.427), because E goes as 1/λ.
THE ELECTRON’S DIRECTION. α = 17 511.9/510 999 = 0.034 27, so cot φ = 1.034 27 × tan 45° = 1.034 27 and φ = 44.03°. The photon went up at 90° and the electron went down at 44°, and momentum balances in both directions — which is the part of the theory that Compton could not test and Bothe and Geiger later could.
WHAT COMPTON ACTUALLY MEASURED, honestly. His paper gives the predicted shift at this geometry as 0.024 Å and the measured shift as 0.022 Å — eight per cent low. He reports it as agreement, and for 1923 it was: the classical theory predicted no shift at all, so a measured 0.022 against a predicted 0.024 settles the question even though the figures do not match to three places. The scanned copy read for this page prints the scattered wavelength itself with an unreadable digit, so that number is deliberately not reproduced here.
AND THE CHECK THAT COSTS MARKS. If a question gives you the incident wavelength in ångströms and you add 2.4263 to it, you are out by a factor of 100. The shift is 0.024 263 Å, not 2.43 Å. This page works in picometres throughout for that reason and prints the ångström value separately.
A 100 keV photon, swept through every angle
| θ | Δλ | λ′ | E′ | electron’s energy | share taken | φ |
|---|---|---|---|---|---|---|
| 0° | 0 pm | 12.3984 pm | 100.000 keV | 0 keV | 0% | 90° (undefined in practice) |
| 15° | 0.0827 pm | 12.4811 pm | 99.338 keV | 0.662 keV | 0.66% | 81.05° |
| 30° | 0.3251 pm | 12.7235 pm | 97.445 keV | 2.555 keV | 2.56% | 72.24° |
| 45° | 0.7107 pm | 13.1091 pm | 94.579 keV | 5.421 keV | 5.42% | 63.65° |
| 60° | 1.2132 pm | 13.6116 pm | 91.087 keV | 8.913 keV | 8.91% | 55.38° |
| 90° | 2.4263 pm | 14.8247 pm | 83.633 keV | 16.367 keV | 16.37% | 39.91° |
| 120° | 3.6395 pm | 16.0379 pm | 77.307 keV | 22.693 keV | 22.69% | 25.77° |
| 180° | 4.8526 pm | 17.2510 pm | 71.871 keV | 28.129 keV | 28.13% | 0° |
The same 90° scatter at eight different energies — the point of the whole page
| Incident photon | λ | Δλ | Δλ/λ | E′ | share the electron takes | where you meet it |
|---|---|---|---|---|---|---|
| 2.5 eV | 495,937 pm | 2.4263 pm | 0.0005% | 2.500 eV | 0.0005% | green light — the shift is 5 parts per million, undetectable |
| 1 keV | 1239.84 pm | 2.4263 pm | 0.196% | 0.998 keV | 0.19% | a soft X-ray; just about measurable |
| 10 keV | 123.984 pm | 2.4263 pm | 1.957% | 9.808 keV | 1.92% | a dental X-ray tube |
| 17.51 keV | 70.800 pm | 2.4263 pm | 3.427% | 16.932 keV | 3.31% | molybdenum Kα — Compton’s own line |
| 100 keV | 12.398 pm | 2.4263 pm | 19.570% | 83.633 keV | 16.37% | diagnostic radiography |
| 662 keV | 1.8729 pm | 2.4263 pm | 129.550% | 288.390 keV | 56.44% | the caesium-137 gamma line |
| 1 MeV | 1.2398 pm | 2.4263 pm | 195.695% | 338.186 keV | 66.18% | a radiotherapy beam |
| 10 MeV | 0.1240 pm | 2.4263 pm | 1956.951% | 486.156 keV | 95.14% | a linac; the photon loses almost everything in one hit |
The shift is a length, not a percentage — and that is the whole lesson
What the experiment showed. Shine X-rays on a light element — Compton used graphite — and look at the scattered beam through a crystal spectrometer. Classical electromagnetism says the scattered radiation must have the same wavelength as the incident radiation: an electron driven at one frequency radiates at that frequency. Compton found a second line at a longer wavelength, and the extra length depended on the angle and on nothing else. Treat the X-ray as a particle with energy hν and momentum h/λ, let it collide elastically with a free electron, conserve energy and momentum relativistically, and Δλ = (h/mec)(1 − cos θ) falls out in four lines. That is why this is the experiment usually credited with establishing that light carries momentum in quanta.
Why there is no incident wavelength in the formula. The collision does not scale with the photon’s wavelength; it scales with the electron’s mass, through the length h/mec. A 1 keV photon and a 10 MeV photon scattered at the same angle both gain 2.43 pm. What differs is what that is worth: 0.2 per cent of the wavelength for the first, nearly 2000 per cent for the second. Nobody detected the effect with visible light not because light behaves differently but because 2.43 pm out of 500 nm is five parts in a million — and that is also the answer to why you cannot see it.
Where this goes wrong. Three places, in order of how often. The first is units: Δλ is 2.43 picometres, which is 0.0243 ångströms and 2.43×10−3 nm, and adding it to a wavelength quoted in ångströms without converting is out by a factor of 100. The second is degrees and radians: cos θ needs θ in radians in any calculator set to radian mode, and cos 90 in radian mode is −0.448, which gives a plausible-looking wrong answer rather than an obvious one. The third is computing the electron’s energy as hc/Δλ; it is E − E′, and those are two large numbers whose difference is small, so keep the figures.
What this page assumes, and what that costs. The electron is taken to be free and at rest, and neither is true. The consequence is visible in Compton’s own data and in every spectrum since: beside the shifted line there is an unshifted one, from photons that scattered off electrons too tightly bound to be knocked free, where the recoiling mass is effectively the whole atom. Put a carbon nucleus into h/mc instead of the electron and the shift becomes about 0.0001 pm — unmeasurable, which is what “unshifted” means. This page does not compute the relative intensity of the two lines; that needs the Klein–Nishina cross-section, which is not in scope here.
How it sits beside the other quantum experiments. The photoelectric effect gives the photon its energy, hν. Compton gives it its momentum, h/λ, and shows that the two obey relativistic collision mechanics. The de Broglie wavelength then turns the statement round and gives momentum to matter. Read in that order the three fit together as one argument, and the Compton shift is the step that makes the photon a particle with a direction rather than just a packet of energy.
Frequently asked questions
Why does a real spectrum show two lines?
Because some electrons are too tightly bound to be treated as free. When the photon scatters off a loosely bound outer electron, the electron is knocked clear, takes the recoil momentum, and the photon comes out at the shifted wavelength this page computes. When it scatters off a tightly bound inner electron, the recoil is taken by the whole atom, whose mass is tens of thousands of times larger. Since the shift goes as 1/m, the shift for an atom is some twenty thousand times smaller — of order 10−4 pm — and the line appears unmoved. Compton saw both lines in graphite in 1923, and the ratio of their intensities depends on the element, which is how you can tell light elements from heavy ones this way.
Can the wavelength ever get shorter?
Not by this formula, which always gives Δλ ≥ 0 because (1 − cos θ) is never negative. The reason is the assumption: the electron starts at rest, so it can only take energy away from the photon. If the electron is already moving fast towards the photon then energy can flow the other way and the photon gains energy — that is inverse Compton scattering, and it is how some astrophysical X-rays are made. This page does not model it, and a question that asks for a decrease in wavelength is asking about a different situation from the one this formula describes.
How much energy can the electron take at most?
At θ = 180°, where the photon is sent straight back. That maximum is called the Compton edge and it is E·2α/(1 + 2α), with α = E/mec². For a 100 keV photon it is 28.13 keV, or 28 per cent; for the 662 keV caesium-137 line it is 478 keV, or 72 per cent; for a 10 MeV photon it is 95 per cent. Set the angle to 180 on this page and the electron row gives it. Notice that it is never 100 per cent: the photon cannot be absorbed outright in a Compton collision, because momentum would not balance. That is the difference from the photoelectric effect, where the atom takes the recoil and the photon does vanish.
Is the Compton effect proof that light is a particle?
It is strong evidence that light carries momentum in discrete amounts of h/λ, which classical wave theory does not provide, and it was taken that way in 1923. Be careful about the word “proof”, though. The derivation treats the photon as a relativistic particle and gets the right answer, and the alternative classical calculation gets a definite wrong answer (no shift at all), so the experiment discriminates between them cleanly. What it does not do is make light stop being a wave: the same crystal spectrometer that measured the shift worked by diffraction, which is wave behaviour, in the same apparatus on the same day.
Related calculators
References
- CODATA Internationally Recommended 2022 Values of the Fundamental Physical Constants, NIST Standard Reference Database 121. Read on 11 November 2026 from the machine-readable table at physics.nist.gov/cuu/Constants/Table/allascii.txt. Every constant on this page comes from that file. It marks h = 6.626 070 15×10−34 J Hz−1, c = 299 792 458 m/s and e = 1.602 176 634×10−19 C as (exact), because the 2019 SI defines the kilogram, the metre and the ampere through them; the masses are measured, the electron being 9.109 383 7139(28)×10−31 kg.
- A. H. Compton, “A Quantum Theory of the Scattering of X-Rays by Light Elements”, The Physical Review, Second Series, Washington University, Saint Louis; submitted December 1922. A scanned copy was read on 11 November 2026 at people.isy.liu.se/jalar/kurser/QF/references/Compton1923.pdf. Verified from it: the paper gives the shift as λθ − λ0 = (2h/mc)sin²(½θ) = 0.0484 sin²(½θ) ångströms, states h/mc = 0.0242 Å, uses the molybdenum Kα line at 0.708 Å, scatters it from graphite at right angles, and reports 0.022 Å (experiment) against 0.024 Å (theory). What could not be read: the scan’s OCR renders the volume and page numbers and one digit of the scattered wavelength illegibly, so this page quotes the volume, page range and that wavelength nowhere. The shift figures above are from legible text.
- The International System of Units (SI), 9th edition, Bureau International des Poids et Mesures, 2019 (the copy read on 11 November 2026 is marked V4.01, June 2026). §2.2 fixes the numerical values of h, c and e, which is why those three carry no uncertainty here while every mass does. A school question that says “take h = 6.63×10−34 J s” is now rounding an exact number rather than quoting a measured one.
- The relative intensity of the shifted and unshifted lines, and the angular distribution of Compton scattering, are governed by the Klein–Nishina cross-section. No source for it was read for this build, so this page computes neither, and nothing here should be used to predict how much scattering happens at a given angle — only what the wavelength and energies are when it does. That is a narrower claim than a radiation-physics page would make, and it is deliberately the narrower one.
